Search results for "phase equilibria"

A New Simple Static Method for the Determination of Solubilities of Condensed Compounds in Supercritical Fluids

2002

Abstract A simple static method based on gravimetric measurements has been adopted to measure the solubility of benzenecarboxylic acid, 2-hydroxy-benzenecarboxylic acid, 4-hydroxy-benzenecarboxylic acid and 1,8-dihydroxyanthraquinone along several isotherms in the temperature range 318–357 K and the pressure interval 7–23 MPa. Solubility data have been correlated with the Zieger–Eckert approach, using the Fedor atomic and group contribution method to estimate the solubility parameter and the molar volume of the solutes. A good agreement was obtained between data reported in the literature and those determined using the proposed method which allows one to measure solubility mole fraction as …

Origin of primitive ultra-calcic arc melts at crustal conditions — Experimental evidence on the La Sommata basalt, Vulcano, Aeolian Islands

2016

International audience; To interpret primitive magma compositions in the Aeolian arc and contribute to a better experimental characterization of ultra-calcic arc melts, equilibrium phase relations have been determined experimentally for the La Sommata basalt (Som-1, Vulcano, Aeolian arc). Som-1 (Na2O + K2O = 4.46 wt.%, CaO = 12.97 wt.%, MgO = 8.78 wt.%, CaO/Al2O3 = 1.03) is a reference primitive ne-normative arc basalt with a strong ultra-calcic affinity. The experiments have been performed between 44 and 154 MPa, 1050 and 1150 °C and from NNO + 0.2 to NNO + 1.9. Fluid-present conditions were imposed with H2O–CO2 mixtures yielding melt H2O concentrations from 0.7 to 3.5 wt.%. Phases encount…

Experimental investigation on peralkaline silicic magmas of Pantelleria Island: inferences on pre-eruptive conditions, magma evolution and water solu…

2017

(Liquid + liquid) equilibria of polymer-salt aqueous two-phase systems for laccase partitioning : UCON 50-HB-5100 with potassium citrate and (sodium …

2012

Aqueous two-phase systems (ATPS) are recognized as very suitable techniques for the recovery of target solutes in biological applications. Three new phase diagrams of (UCON 50-HB-5100 + potassium citrate + water), (UCON 50-HB-5100 + sodium formate + water), and (UCON 50-HB-5100 + potassium formate + water) systems were measured at 23 C. The binodal curves were successfully described using the empirical equation suggested by Merchuk and co-workers. The reliability of the tie-line data experimentally determined was evaluated using the equations reported by Othmer–Tobias and Bancroft and satisfactory linearity was obtained for all ATPS. Among the salts studied, potassium citrate proved to be t…

Phase equilibrium constraints on pre-eruptive conditions of recent felsic explosive volcanism at Pantelleria Island, Italy.

2010

International audience; We present experimental phase equilibria carried out on a pantelleritic bulk-rock composition with a peralkalinity index [PI = molar (Na2O + K2O)/Al2O3] = 1*4, which is representative of the most energetic pumice fall eruption of the resurgent post-caldera volcanism on Pantelleria island. For the explored conditions (P = 25-150 MPa; T = 680-800°C; H2Omelt up to 6 wt %; fO2 ≤ NNO, where NNO is nickel-nickel oxide buffer) clinopyroxene is the liquidus phase followed by alkali feldspar and then quartz. The crystallization of amphibole is limited to temperatures below 700°C. Aenigmatite crystallizes near the liquidus for P ≥ 100 MPa. When clinopyroxene is the sole liquid…

Experimental Crystallization of a High-K Arc Basalt: the Golden Pumice, Stromboli Volcano (Italy)

2006

International audience; The near-liquidus crystallization of a high-K basalt (PST-9 golden pumice, 49·4 wt % SiO2, 1·85 wt % K2O, 7·96 wt % MgO) from the present-day activity of Stromboli (Aeolian Islands, Italy) has been experimentally investigated between 1050 and 1175°C, at pressures from 50 to 400 MPa, for melt H2O concentrations between 1·2 and 5·5 wt % and {Delta}NNO ranging from –0·07 to +2·32. A drop-quench device was systematically used. AuPd alloys were used as containers in most cases, resulting in an average Fe loss of 13% for the 34 charges studied. Major crystallizing phases include clinopyroxene, olivine and plagioclase. Fe–Ti oxide was encountered in a few charges. Clinopyro…

Pre-Eruptive Conditions of La Sommata Basalt (Vulcano, Aeolian Islands): Constraints from Experimental Petrology.

2011

One of the most primitive magma of Aeolian Arc is the basalt erupted (about 50 ka B.P.) by the La Sommata scoria cone at Vulcano; this is a silica-undersaturated (ne-normative) low-phyric (10-20 wt. %), Ca-rich (CaO = 13 wt. %) shoshonitic basalt (K2O = 2.28 wt.%) in which olivine phenocrysts host melt inclusions more primitive than whole rock composition and with an ultra-calcic character: CaO/Al2O3 > 1.4 [Métrich and Clocchiatti, 1996; Gioncada et al., 1998; Schiano et al., 2000]. Phenocrysts mainly include olivines (Fo92) and clinopyroxenes (Fs5). Plagioclase microlites (from An79 to An67) are the most abundant groundmass phase (45 wt. %), together with clinopyroxene (Fs11) and olivine (…